Liquid Nitrogen

Nitrogen Gas Converted Into A Liquid State And Used For Cooling And Preserving Various Logistic Materials

Liquid Nitrogen

Liquid nitrogen is inert, colorless, odorless, non-corrosive, non-flammable, and exceptionally cold. Nitrogen is a primary component of the atmosphere (78.03% by volume and 75.5% by weight). Despite its inert properties and inability to support combustion, nitrogen does not support life.

Under normal conditions, nitrogen remains inert but can react at high temperatures with highly reactive metals like lithium and magnesium to form nitrides. It can also react with oxygen to form nitrogen oxides and combine with hydrogen in the presence of a catalyst to produce ammonia.

Nitrogen is non-corrosive, so special anti-corrosion materials are not necessary. However, materials must be carefully selected to withstand the low temperatures associated with liquid nitrogen. Containers and pipelines must comply with the specifications of the American Society of Mechanical Engineers (ASME) or the Department of Transportation (DOT) regulations and meet the standards required for pressure and temperature.

Nitrogen is primarily used in its gaseous state but is often stored and transported as a liquid to improve cost efficiency in product delivery.

Liquid nitrogen is classified as a cryogenic liquid, referring to liquefied gases with typical boiling points below –130°F (–90°C). Specifically, liquid nitrogen boils at –320°F (–196°C). Due to the significant temperature difference between the product and the surrounding environment, specialized equipment is essential for safe storage and handling, even during colder seasons.

Typical systems generally include the following essential components: a cryogenic storage tank, one or more vaporizers, and a pressure and temperature control system. Cryogenic storage tanks are designed similarly to vacuum flasks and are intricately engineered to shield the inner container from external heat. Vaporizers convert liquid nitrogen into ambient-temperature gas, while pressure control manifolds regulate the gas pressure delivered to processes. In some processes using liquid nitrogen, vaporizers or pressure control manifolds may not be required.

Physical and Chemical Properties of Liquid Nitrogen

  • Molecular Weight: 28.01
  • Boiling Point at 1 atm: -320.5°F (-195.8°C, 77 K)
  • Freezing Point at 1 atm: -346.0°F (-210.0°C, 63 K)
  • Critical Temperature: -232.5°F (-146.9°C)
  • Critical Pressure: 492.3 psia (33.5 atm)
  • Liquid Density at Boiling Point, 1 atm: 50.45 lb/scf
  • Gas Density at 68°F (20°C), 1 atm: 0.0725 lb/scf
  • Specific Gravity of Gas (Air = 1) at 68°F (20°C), 1 atm: 0.967
  • Specific Gravity of Liquid (Water = 1) at 68°F (20°C), 1 atm: 0.808
  • Specific Volume at 68°F (20°C), 1 atm: 13.80 scf/lb
  • Heat of Vaporization: 2399 BTU/lb mole
  • Expansion Ratio from Liquid to Gas (at Boiling Point to 68°F/20°C): 1:694

Containers

The provided image depicts a typical cryogenic liquid container. These containers are essentially insulated pressure vessels with a vacuum jacket. They are equipped with safety relief valves and rupture disks to protect the container from excessive pressure buildup.

Cryogenic liquid containers operate at pressures up to 350 psig and have liquid capacities ranging from 80 to 450 liters. The product can be withdrawn as a gas through an internal vaporizer or as a liquid under its own vapor pressure.

Liquid Nitrogen Storage Tank at Batam, Indonesia

Liquid Nitrogen Cryogenic at Batam, Indonesia

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